教育经历： 1993-1997 中国农业大学应用化学系, 理学学士 1997-2002 中国农业大学应用化学系, 理学博士 工作经历： 2002-2004 中国科学院上海有机化学研究所, 博士后 2004-2006 德国马普所(Muelheim), Research Associate 2006-2008 美国加州大学洛杉矶分校, 博士后 2008-2009 美国伊利诺伊大学厄本那-香槟分校, Research Associate 2009-2010 美国加州大学洛杉矶分校, 访问学者 2010-2011 中国农业大学理学院应用化学系，副教授 2011-至今 中国农业大学理学院应用化学系，教授 研究方向及兴趣： 1. 研究金属和有机小分子催化的环加成及环化反应，特别是基于1,3-偶极子的高效、高选择性环加成反应，发展高效的选择性合成方法，并利用手性金属催化剂和手性有机小分子催化剂发展高效和高选择性的不对称合成新方法，研究这些方法在杂环分子及复杂生物活性分子合成中的应用。 2. 合成具有重要生物活性的杂环化合物及天然产物，用于杀虫剂、除草剂、杀菌剂及植物生长调节剂等的研究，开展新农药创制工作。 3. 研究农药的创新合成工艺。 研究及教学工作简介： 以新农药创制和农药绿色合成为导向，以构建多样性杂环小分子库为目标，研究基于两性离子的环加成及环化反应和多样性导向合成，发展高选择性、经济、高效的合成杂环化合物的方法学，构建具有骨架结构多样性、官能团多样性、立体化学多样性的杂环化合物库，开展生物活性研究。已在J. Am. Chem. Soc.、Angew. Chem. Int. Ed.、ACS Catal.、Chem. Sci.、Chem. Rev.等刊物上发表论文 150 余篇， 获得5项中国发明专利授权。研究成果被Synfact、Organic Chemistry Portal 和 《有机化学》 等作为亮点评述。 长期主讲本科生课程《有机化学B》，已培养10余名研究生，其中多人次获得国家奖学金，三人次的论文被评为中国农业大学校级优秀硕士或博士学位论文。多次获得本科生“百篇优秀毕业论文（设计）”和“国家大学生创新性实验计划”项目优秀指导教师奖，所培养本科生八人次获得校级优秀毕业论文。 |
发表的论文及著作：1. Kuan Li, Shuo Zhen, Wang Wang, Juan Du, Songcheng Yu, Yongjun Wu, and Hongchao Guo,* “A fungicide-inspired precursors of π-allylpalladium intermediates for palladium-catalyzed decarboxylative cycloadditions”, Chem. Sci. 2023, 14, 3024–3029. 2. Lan Wang, Min Liu, Mengxi Lu, Bo Wang, Qihuan Han, Jingrong Jin, Songcheng Yu, Yongjun Wu and Hongchao Guo,* “Palladium-Catalyzed [4+2] Cycloaddition of Amido-Tethered Allylic Carbonates with Oxazol-5-(4H)-ones: Synthesis of Piperidine-2,6-dione Derivatives”, Org. Chem. Front. 2023, 10, 813−818. 3. Jiaqing Xu, Min Liu, Yimin Hu, Lei Wang, Wei Wang, Yongjun Wu, Hongchao Guo,* “Palladium-catalyzed allylic alkylation of hydrazones with hydroxy-tethered allyl carbonates: synthesis of functionalized hydrazones”, Org. Chem. Front. 2022, 9, 5851−5857. 4. Wangyu Shi, Yue Ren, Haoran Zhao, Yi Tang, Shixiang Piao, Biming Mao, Wei Wang, Yongjun Wu, Bo Wang, Hongchao Guo,* “Phosphine-Catalyzed (4+2) Annulation of Allenoates with Benzofuran-Derived Azadienes and Subsequent Thio-Michael Addition”, Org. Lett. 2022, 24, 3747−3752. 5. Sen Yang, Kuan Li, Yi Tang, Bing Zheng, Wei Wang, Yongjun Wu, Yumei Xiao and Hongchao Guo,* “Palladium-Catalyzed (5+3) Annulation of 4-Vinyl-4-butyrolactones with C,N-Cyclic Azomethine Imines: Construction of Eight-Membered Ring”, Adv. Synth. Catal. 2022, 364, 3967−3972. 6. Kuan Li, Sen Yang, Bing Zheng,* Wei Wang, Yongjun Wu, Jing Li, Hongchao Guo,* “A new type of delta-vinylvalerolactone for palladium-catalyzed cycloaddition: synthesis of nine-membered heterocycles”, Chem. Commun. 2022, 58, 6646−6649. 7. Jianning Liao, Qihuan Han, Min Liu, Wangyu Shi, Jiaqing Xu, Wei Wang, Yongjun Wu, Hongchao Guo, “Phosphine-Catalyzed (4+2) Annulation of Alkenes with Acidic Hydrogen-Tethered Allylic Carbonates”, Adv. Synth. Catal. 2022, 364, 3283−3288. 8. Jiaqing Xu, Wangyu Shi, Min Liu, Jianning Liao, Wei Wang, Yongjun Wu and Hongchao Guo,* “Palladium-Catalyzed [4+2] Cycloaddition of Hydroxy-Tethered Allylic Carbonates with Alkenes: Synthesis of Functionalized Tetrahydropyrans”, Adv. Synth. Catal. 2022, 364, 2060−2066. 9. Bo Wang, Yimin Hu, Hongchao Guo* and Lei Tao,* "Synthesis of Chromone-Spiroindolinone-Cyclopentene Derivatives through Phosphine-Catalyzed (3+2) Annulation of Morita–Baylis–Hillman Carbonates with Oxindole–Chromones", ChemistrySelect 2022, 7, e202203340. 10. Biming Mao, Jiaqing Xu, Wangyu Shi, Wei Wang, Yongjun Wu, Yumei Xiao,* Hongchao Guo,* “Pd-Catalyzed [4+2] cycloaddition of methylene cyclic carbamates with dihydropyrazolone-derived alkenes: synthesis of spiropyrazolones”, Org. Biomol. Chem. 2022, 20, 4086−4090. 11. Jiaqing Xu, Yimin Hu, Jianning Liao, Juan Du, Lei Wang, Wei Wang, Yongjun Wu and Hongchao Guo,* "Synthesis of Fluoroalkyl Cyclopentenes: Highly Diastereoselective Phosphine-Catalyzed [3+2] Annulation of β-Fluoroalkylvinyl Arylsulfones with Morita-Baylis-Hillman Carbonates", ChemistrySelect 2022, 7, e202203184. 12. Min Liu, Jianning Liao, Yujie Dong, Wangyu Shi, Yimin Hu, Jiaqing Xu, Wei Wang, Yong Xu,* Hongchao Guo,* “Acidic Hydrogen-Tethered Allylic Carbonates for Phosphine-Catalyzed (4+2) Annulation of Sulfamate-Derived Cyclic Imines”, Adv. Synth. Catal. 2022, 364, 2146−2151. 13. Jianning Liao, Jiaqing Xu, Yongjun Wu, Yuxia Hou, Hongchao Guo,* “DMAP-Catalyzed (3+2) Annulation of Pyrazoledione-Derived Morita–Baylis–Hillman Carbonates with 2-Arylideneindane-1,3-diones: An Access to Dispirocyclic Compounds”, Adv. Synth. Catal. 2022, 364, 1074−1079. 14. Zhenzhen Gao,* Lei Xie, Lusha Ji, Xin Ma, Xiaojing Li, Honglei Liu,* Hongchao Guo, “Phosphine-catalyzed [3+2] annulation of beta-sulfonamido-substituted enones with trans-alpha-cyano-alpha,beta-unsaturated ketones for the synthesis of highly substituted pyrrolidines”, RSC Adv. 2021, 11, 40136−40139. 15. Leijie Zhou, Xue Zhang, Qijun Wang, Min Liu, Wei Wang, Yongjun Wu, Liezhong Chen,* Hongchao Guo,* “Phosphine-Catalyzed Asymmetric Tandem Isomerization/Annulation of Allyl Amines with Allenoates: Enantioselective Annulation of Saturated C-N Bond”, Org. Lett. 2021, 23, 9173−9178. Featured in Org. Chem. Highlights: C-N Ring Construction, 2022, April, 11. 16. Min Liu, Leijie Zhou, Wangyu Shi, Yimin Hu, Jianning Liao, Zeqing Duan, Wei Wang, Yongjun Wu, Bing Zheng,* Hongchao Guo,* “Phosphine-Catalyzed (4+2) Annulation of δ-Sulfonamido-Substituted Enones with 1,1-Dicyanoalkenes: Synthesis of Piperidine Derivatives”, Org. Lett. 2021, 23, 7703−7707. 17. Yimin Hu, Wangyu Shi, Zhengyang Yan, Jianning Liao, Min Liu, Jiaqing Xu, Wei Wang, Yongjun Wu, Cheng Zhang,* Hongchao Guo,* “Base-Catalyzed Sequential 1,4-Addition/Intramolecular Cyclization/Aromatization: Synthesis of Benzofuro[3,2-b]pyridines”, Org. Lett. 2021, 23, 6780−6783. 18. Yimin Hu, Zhengyang Yan, Wangyu Shi, Jianning Liao, Min Liu, Ting Pan, Wei Wang, Yongjun Wu, Xianghong Hao,* Hongchao Guo,* “Copper/Lewis base cooperatively catalyzed asymmetric allylic alkylation of Morita−Baylis−Hillman carbonates with azomethine ylides”, Chem. Commun. 2021, 57, 8059−8062. 19. Ting Pan, Xing Gao, Sen Yang, Lan Wang, Yimin Hu, Min Liu, Wei Wang, Yongjun Wu, Bing Zheng, Hongchao Guo,* “Palladium-Catalyzed (3+3) Annulation of Allenylethylene Carbonates with Nitrile Oxides”, Org. Lett. 2021, 23, 5750−5754. 20. Hongxiang Li, Wangyu Shi, Chang Wang, Hao Liu, Wei Wang, Yongjun Wu, Hongchao Guo,* “Phosphine-Catalyzed Cascade Annulation of MBH Carbonates and Diazenes: Synthesis of Hexahy-drocyclopenta[c]pyrazole Derivatives”, Org. Lett. 2021, 23, 5571−5575. 21. Xianghong Hao, Hongchao Guo,* “Vinyl Methylene Cyclic Carbonate: A New Type of Synthon for Pd-Catalyzed Cycloaddition Reactions”, Chin. J. Org. Chem. 2021, 41, 2134−2135. 22. Xing Gao, Dongyu Zhu, Feng Jiang, Jianning Liao, Wei Wang, Yongjun Wu, Lufei Zheng,* Hongchao Guo,* Palladium-Catalyzed Stereoselective (3+2) Cycloaddition of Vinylethylene Carbonates with Cyclic N-Sulfonyl Ketimines, Org. Biomol. Chem. 2021, 19, 4877−4881. 23. Yali Wang, Hongchao Guo,* “Hydrogen-Bonding-Promoted Cascade Rearrangement”, Chin. J. Org. Chem. 2021, 41, 433−434. 24. Hongxiang Li, Honglei Liu,* Hongchao Guo,* “Recent Advance in Phosphonium Salt Catalysis”, Adv. Synth. Catal. 2021, 363, 2023−2036. 25. Lan Wang, Feng Jiang, Xing Gao, Wei Wang, Yongjun Wu, Hongchao Guo, Bing Zheng,* Base-mediated decarboxylative [3+2] annulation of ethynyl benzoxazinanones and benzimidamides: synthesis of imidazole derivatives, Adv. Synth. Catal. 2021, 363, 2066−2070. 26. Hao Deng, Yujie Dong, Yu Shangguan, Fazhou Yang, Sheng Han, Jiaqi Wu, Bo Liang, Hongchao Guo, Cheng Zhang,* Copper-Catalyzed Three-Component Carboboronation of Allenes Using Highly Strained Cyclic Ketimines as Electrophiles, Org. Lett. 2021, 23, 4431−4435. 27. Chunhao Yuan,* Huimin Yang, Qi Gong, Shan Luo, Jing Gu, Yanqing Ge, Hongchao Guo,* Lei Xie, Brønsted Base-Catalyzed Tandem [2+4] Annulation/1,3-Proton Shift/Aromatization Reaction of α-Alkylidene Succinimides with 5-Alkenyl Thiazolones, Adv. Synth. Catal. 2021, 363, 3336−3347. 28. Jianning Liao, Jipan Dong, Jiaqing Xu, Wei Wang, Yongjun Wu, Yuxia Hou,* Hongchao Guo,* “Phosphine-Catalyzed [3+2] Annulation of Morita-Baylis-Hillman Carbonates with Isoxazole-Based Alkenes”, J. Org. Chem. 2021, 86, 2090−2099. 29. Yifan Huang, Jianning Liao, Wei Wang, Honglei Liu,* Hongchao Guo,* “Synthesis of heterocyclic compounds through nucleophilic phosphine catalysis”, Chem. Commun. 2020, 56, 15235−15281. 30. Hui Jiang, Leijie Zhou, Biming Mao, Chunhao Yuan, Wei Wang, Yongjun Wu, Cheng Zhang,* Hongchao Guo,* “Organocatalytic Enantioselective [3+2] Cycloaddition of Azomethine Ylides with 2,4-Dienals: Construction of Remote Stereogenic Centers via 1,6-Addition Reaction”, Adv. Synth. Catal. 2020, 362, 5716−5720. 31. De Zhong, Feng Jiang, Siyong Shen, Lan Wang, Wei Wang, Yongjun Wu, Yumei Xiao,* Hongchao Guo,*“Formal [3+2] Annulation of Copper-Allenylidenes with 3-Oxo-3-Arylpropanenitriles: Synthesis of Tetrasubstituted Furans”, Adv. Synth. Catal. 2020, 362, 5026−5030. Featured in Org. Chem. Highlights: Heteroaromatics 2021, October, 11. 32. Yimin Hu, Wangyu Shi, Bing Zheng, Jianning Liao, Wei Wang, Yongjun Wu, Hongchao Guo,* "Organocatalytic Asymmetric C(sp2)–H Allylic Alkylation: Enantioselective Synthesis of Tetrasubstituted Allenoates", Angew. Chem. Int. Ed. 2020, 59, 19820−19824. 33. Biming Mao, Honglei Liu, Zhengyang Yan, Yi Xu, Jiaqing Xu, Wei Wang, Yongjun Wu, Hongchao Guo,* “Palladium-Catalyzed Asymmetric [4+2] Cycloaddition of 2-Methylidenetrimethylene Carbonate with Alkenes: Access to Chiral Tetrahydropyran-Fused Spirocyclic Scaffolds”, Angew. Chem. Int. Ed. 2020, 59, 11316−11320. 34. Xing Gao, Dongyu Zhu, Yuehua Chen, Hao Deng, Feng Jiang, Wei Wang, Yongjun Wu, Hongchao Guo,* “Palladium-Catalyzed [5+2] Annulation of Vinylethylene Carbonates with Barbiturate-Derived Alkenes”, Org. Lett. 2020, 22, 7158−7163. 35. Yunyao Zhu, Jiangjiexing Wu, Lijun Han, Xiaoyu Wang, Wei Li, Hongchao Guo,* Hui Wei,* “Nanozyme Sensor Arrays Based on Heteroatom-Doped Graphene for Detecting Pesticides”. Anal. Chem. 2020, 92,7444−7452. 36. Wangyu Shi, Biming Mao, Jiaqing Xu, Qijun Wang, Wei Wang, Yongjun Wu, Xuefeng Li, Hongchao Guo,* Phosphine-Catalyzed Cascade Michael Addition/[4+2] Cycloaddition Reaction of Allenoates and 2-Arylidene-1,3-indanediones, Org. Lett. 2020, 22, 2675−2680 (Corrections, See: Org. Lett. 2021, 23, 6600). 37. Fazhou Yang, Ziyan Liu, Hao Liu, Shangguan Yu, Hao Deng, Jiaxing Huang, Yumei Xiao, Hongchao Guo, Cheng Zhang,* "Cu-Catalysed synthesis of benzo[f]indole-2,4,9(3H)-triones by the reaction of 2-amino-1,4-napthoquinones with alpha-bromocarboxylates", Org. Biomol. Chem. 2020, 18, 6724−6731. 38. Huihui Zhang, Xing Gao, Feng Jiang, Wangyu Shi, Wei Wang, Yongjun Wu, Cheng Zhang, Xueyan Shi,* Hongchao Guo,* “Palladium-Catalyzed Asymmetric [3+2] Cycloaddition of Vinylethylene Carbonates with 2-Arylidene-1,3-Indandiones: Synthesis of Tetrahydrofuran-Fused Spirocyclic 1,3-Indandiones”, Eur. J. Org. Chem. 2020, 4801−4804. 39. Wangyu Shi, Jiaqing Xu, Biming Mao, Hao Jia, Jiaxing Huang,* Hongchao Guo,* “[3+2] Cycloaddition of Methylenedihydrobenzofurandiones and Nitrilimines: Synthesis of Sipropyrazole Compounds”, Chin. J. Org. Chem. 2020, 40, 756−762. 40. Biming Mao, Junya Zhang, Yi Xu, Zhengyang Yan, Wei Wang, Yongjun Wu, Changqing Sun, Bing Zheng, Hongchao Guo,* “Palladium-catalyzed [3+2] annulation of allenyl carbinol acetates with C,N-cyclic azomethine imines”, Chem. Commun. 2019, 55, 12841−12844. 41. Chang Wang, Yuehua Chen, Jingyu Li, Leijie Zhou, Bo Wang, Yumei Xiao, Hongchao Guo,* “Phosphine-Catalyzed Asymmetric Cycloaddition Reaction of Diazenes: Enantioselective Synthesis of Chiral Dihydropyrazoles”, Org. Lett. 2019, 21, 7519−7523. 42. Leijie Zhou, Yuan Zeng, Xing Gao, Qijun Wang, Chang Wang, Bo Wang, Wei Wang, Yongjun Wu, Bing Zheng,* Hongchao Guo,* “A chiral squaramide-catalyzed asymmetric dearomative tandem annulation reaction through a kinetic resolution of MBH alcohols: highly enantioselective synthesis of three-dimensional heterocyclic compounds”, Chem. Commun. 2019, 55, 10464−10467. 43. Leijie Zhou, Chunhao Yuan, Yuan Zeng, Qijun Wang, Chang Wang, Min Liu, Wei Wang, Yongjun Wu, Bing Zheng,* Hongchao Guo,* “Direct Activation of Unmodified Morita-Baylis-Hillman Alcohols through Phosphine Catalysis for Rapid Construction of Three-Dimensional Heterocyclic Compounds”, Org. Lett. 2019, 21, 4882−4886. 44. Hao Deng, Ziwei Meng, Sifan Wang, Zheming Zhang, Yaqi Zhang, Yu Shangguan, Fazhou Yang, Dekai Yuan, Hongchao Guo, Cheng Zhang,* “Enantioselective Copper-Catalyzed Three-Component Carboboronation of Allenes: Access to Functionalized Dibenzo [b,f][1,4]oxazepine Derivatives”, Adv. Synth. Catal. 2019, 361, 3582–3587. 45. Jiaqing Xu, Wenjun Yang, Wangyu Shi, Biming Mao, Yan Lin, Yumei Xiao,* Hongchao Guo,* “DMAP-catalyzed [4+2] annulation of alpha-substituded allenoates with unsaturated pyrazolones”, Tetrahedron 2019, 75, 3609−3616. 46. Biming Mao, Yi Xu, Yuehua Chen, Jipan Dong, Junya Zhang, Kejia Gu, Bing Zheng, Hongchao Guo,* “Palladium-Catalyzed Asymmetric Tandem [3+2] Cycloaddition/Allylation Reaction of Methylene-Trimethylenemethane: Access to Chiral Tricyclic Dinitrogen-Fused Heterocycles”, Org. Lett. 2019, 21, 4424−4427. 47. Xing Gao, Miaoren Xia, Chunhao Yuan, Leijie Zhou, Wei Sun, Cheng Li, Bo Wu, Dongyu Zhu, Cheng Zhang, Bing Zheng, Dongqi Wang, Hongchao Guo,* “Enantioselective Synthesis of Chiral Medium-Sized Cyclic Compounds via Tandem Cycloaddition/Cope Rearrangement Strategy”, ACS Catal. 2019, 9, 1645−1654. 48. Bo Wang, Qijun Wang, Honglei Liu, Jianning Liao, Jiaxing Huang,* Hongchao Guo,* “Synthesis of Dihydropyrano[3,2-c]pyrazolone through 1,3-Dipolar Cycloaddition of Nitrilimines with Methyl Coumalate”, Chin. J. Org. Chem. 2019, 39, 1354−1361. 49. Wangyu Shi, Leijie Zhou, Biming Mao, Qijun Wang, Chang Wang, Cheng Zhang, Xuefeng Li, Yumei Xiao,* Hongchao Guo,* “Phosphine-Catalyzed [3+2] Annulation of β-Sulfonamido-Substituted Enones with Sulfamate-Derived Cyclic Imines”, J. Org. Chem. 2019, 84, 679−686. 50. Honglei Liu, Yan Lin, Yan Zhao, Miaoren Xiao, Leijie Zhou, Qijun Wang, Cheng Zhang, Dongqi Wang, Ohyun Kwon,* Hongchao Guo,* “Phosphine-Promoted [4 + 3] Annulation of Allenoate with Aziridines for Synthesis of Tetrahydroazepines: Phosphine-Dependent [3 + 3] and [4 + 3] Pathways”, RSC Adv. 2019, 8, 1214−1221. 51. Wei Sun, Feng Jiang, Honglei Liu, Xing Gao, Hao Jia, Cheng Zhang,* Hongchao Guo,* “Double [3+2] Cycloaddition of Nitrile Oxides with Allenoates: Synthesis of Spirobidihydroisoxazoles”, Chin. Chem. Lett. 2019, 30, 363–366. 52. Qijun Wang, Bo Wang, Hao Deng, Yu Shangguan, Yan Lin, Yaqi Zhang, Zheming Zhang, Yumei Xiao, Hongchao Guo, Cheng Zhang,* “Silver-Catalyzed Three-Component Difunctionalization of Alkenes via Radical Pathways: Access to CF3-Functionalized Alkyl Substituted 1,4-Naphthoquinone Derivatives”, J. Org. Chem. 2019, 84, 1006−1014. 53. Yan Lin, Qijun Wang, Yang Wu, Chang Wang, Hao Jia, Cheng Zhang, Jiaxing Huang,* Hongchao Guo,* “Pd-Catalyzed [3+2] Cycloaddition of Vinylcyclopropanes with 1-Azadienes: Synthesis of 4-Cyclopentylbenzo[e][1,2,3]oxathiazine 2,2-Dioxides”, RSC Adv. 2018, 8, 40798–40803. 54. Hongchao Guo,* Yi Chiao Fan, Zhanhu Sun, Yang Wu, Ohyun Kwon,* “Phosphine Organocatalysis”, Chem. Rev. 2018, 118, 10049−10293. 55. Leijie Zhou, Chang Wang, Chunhao Yuan, Honglei Liu, Cheng Zhang, Hongchao Guo,* “Phosphine-Catalyzed [3+2] Annulation of 2-Hydroxy-1,4-Naphthaquinones and Allenoate: An Allene-Alkene [3+2] Annulation Mechanism Involving Consecutive γ-Addition–Aldol Reaction”, Org. Lett. 2018, 20, 6591−6595. 56. Yuan Zeng, Leijie Zhou, Xing Gao, Yang Wu, Qijun Wang, Zhenyan Guo, Jiaxing Huang,* Hongchao Guo,* “Diastereodivergent Synthesis of Pyrazoline Derivatives through [3+2] Cycloaddition of Baylis-Hillman Adducts and Nitrilimines”, J. Heterocyclic Chem. 2018, 55, 2781−2791. 57. Feng Jiang, Xinping Feng, Rou Wang, Xing Gao, Hao Jia, Yumei Xiao, Cheng Zhang,* Hongchao Guo,* “Asymmetric [3+3] Annulation of Copper−Allenylidenes with Pyrazolones: Synthesis of Chiral 1,4-Dihydropyrano[2,3-c]pyrazoles”, Org. Lett. 2018, 20, 5278–5281. 58. Zhenzhen Gao, Chang Wang, Leijie Zhou, Chunhao Yuan, Yumei Xiao, Hongchao Guo,* “Phosphine-Catalyzed [8+2]-Annulation of Heptafulvenes with Allenoates and Its Asymmetric Variant: Construction of Bicyclo[5.3.0]decane Scaffold”, Org. Lett. 2018, 20, 4302–4305. 59. Qijun Wang, Chang Wang, Wangyu Shi, Yumei Xiao,* Hongchao Guo,* “Pd-Catalyzed Diastereoselective [3+2] Cycloaddition of Vinylcyclopropanes with Sulfamate-Derived Cyclic Imines”, Org. Biomol. Chem. 2018, 16, 4881–4887. 60. Hao Jia, Zhenyan Guo, Honglei Liu, Biming Mao, Xueyan Shi,* Hongchao Guo,* “Tandem Nucleophilic Addition–Cycloaddition of Arynes with α-Iminoesters: Two Concurrent Pathways to Imidazolidines”, Chem. Commun. 2018, 54, 7050–7053. 61. Honglei Liu, Hao Jia, Wangyu Shi, Chang Wang, Cheng Zhang, Hongchao Guo,* “Nickel (II)-Catalyzed [8+3] Cycloaddition of 2-Aryl-N-tosyl-aziridines with Tropone”, Org. Lett. 2018, 20, 3570–3573. 62. Zhenyan Guo, Hao Jia, Honglei Liu, Qijun Wang, Jiaxing Huang, Hongchao Guo,* “A [4+3] Annulation Reaction of aza-o-Quinone Methides with Arylcarbohydrazonoyl Chlorides for Synthesis of 2,3-Dihydro-1H-benzo[e][1,2,4]triazepines”, Org. Lett. 2018, 20, 2939–2943. 63. Chang Wang, Yan Li, Yang Wu, Qijun Wang, Wangyu Shi, Chunhao Yuan, Leijie Zhou, Yumei Xiao, Hongchao Guo,* “Enantioselective Construction of Tetrahydroquinazoline Motifs via Palladium-Catalyzed [4+2] Cycloaddition of Vinyl Benzoxazinones with Sulfamate-Derived Cyclic Imines”, Org. Lett. 2018, 20, 2880–2883. 64. Chunhao Yuan, Yang Wu, Dongqi Wang, Zhenhua Zhang, Chang Wang, Leijie Zhou, Cheng Zhang, Baoan Song, Hongchao Guo,* “Formal [5+3] Cycloaddition of Zwitterionic Allylpalladium Intermediates with Azomethine Imines for Construction of N,O-Containing Eight-Membered Heterocycles”, Adv. Synth. Catal. 2018, 360, 652–658. 65. Leijie Zhou, Chunhao Yuan, Yuan Zeng, Honglei Liu, Chang Wang, Xing Gao, Qijun Wang, Cheng Zhang, Hongchao Guo,* “Phosphine-Catalyzed [5+1] Annulation of δ-Sulfonamido-Substituted Enones with N-Sulfonylimines: A Facile Synthesis of Tetrahydropyridines”, Chem. Sci. 2018, 9, 1831–1835. 66. Chang Wang, Zhenzhen Gao, Leijie Zhou, Qijun Wang, Yang Wu, Chunhao Yuan, Jianning Liao, Yumei Xiao, Hongchao Guo,* “Multifunctional Chiral Phosphine-Catalyzed [3+2] Annulation of Morita–Baylis–Hillman Carbonates with Cyclopentenones: Asymmetric Synthesis of 4-oxo-Hexahydropentalenes”, Chem. Commun. 2018, 54, 279–282. 67. Biming Mao, Wangyu Shi, Jianning Liao, Honglei Liu, Cheng Zhang, Hongchao Guo,* “Phosphine-Catalyzed [4+2] Annulation of Allenoate with Sulfamate-Derived Cyclic Imines: A Reaction Mode Involving γ’-Carbon of α-Substituted Allenoate”, Org. Lett. 2017, 19, 6340–6343. 68. Yang Wu, Chunhao Yuan, Chang Wang, Biming Mao, Hao Jia, Xing Gao, Jianning Liao, Feng Jiang, Leijie Zhou, Qijun Wang, Hongchao Guo,* “Palladium-Catalyzed [5+2] Cycloaddition of Vinyloxiranes with Sulfamate-Derived Cyclic Imines to Construct 1,3-Oxazepine Heterocycles”, Org. Lett. 2017, 19, 6268–6271. 69. Hao Jia, Honglei Liu, Zhenyan Guo, Jiaxing Huang, Hongchao Guo,* “Tandem [3+2] Cycloaddition/1,4-Addition Reaction of Azomethine Ylides and aza-ortho-Quinone Methides for Asymmetric Synthesis of Imidazolidines”, Org. Lett. 2017, 19, 5236−5239. 70. Honglei Liu, Hao Jia, Bo Wang, Yumei Xiao, Hongchao Guo,* “Synthesis of Spirobidihydropyrazole through Double 1,3-Dipolar Cycloaddition of Nitrilimines with Allenoates”, Org. Lett. 2017, 19, 4714−4717. 71. Xing Gao, Zhen Li, Wenjun Yang, Yang Liu, Wufeng Chen, Cheng Zhang, Lufei Zheng,* Hongchao Guo,* “Phosphine-Catalyzed [3+2] and [4+2] Annulation Reactions of Ynones with Barbiturate-derived Alkenes for Synthesis of Spirobarbiturates and Dihydropyranopyrimidinediones”, Org. Biomol. Chem. 2017, 15, 5298–5307. 72. Honglei Liu, Yan Zhao, Zhen Li, Hao Jia, Cheng Zhang, Yumei Xiao, Hongchao Guo,* “Lewis Base-Catalyzed Diastereoselective [3+2] Cycloaddition Reaction of Nitrones with Electron-Deficient Alkenes: An Access to Isoxazolidine Derivatives”, RSC Adv. 2017, 7, 29515–29519. 73. Lei Zhang, Wenjun Yang, Leijie Zhou, Yang Liu, Honglei Liu, Yumei Xiao, Hongchao Guo,* “Phosphine-Catalyzed Diastereoselective [3+3] Annulation of Morita–Baylis–Hillman Carbonates with C,N-Cyclic Azomethine Imines”, J. Heterocyclic Chem. 2017, 54, 3377–3388. 74. Bo Wang, Honglei Liu, Qijun Wang, Chunhao Yuan, Hao Jia, Chunxiao Liu, Hongchao Guo,* “Thermal [3+2] Cycloaddition of Phthalazinium Dicyanomethanide with Allenoates”, Tetrahedron 2017, 73, 5926–5931. 75. Leijie Zhou, Chunhao Yuan, Cheng Zhang, Lei Zhang, Zhenzhen Gao, Chang Wang, Honglei Liu, Yang Wu, Hongchao Guo,* “Enantioselective Synthesis of Quinazoline-Based Heterocycles through Phosphine-Catalyzed Asymmetric [3+3] Annulation of Morita−Baylis−Hillman Carbonates with Azomethine Imines”, Adv. Synth. Catal. 2017, 359, 2316–2321. 76. Wenjun Yang, Wei Sun, Cheng Zhang, Qijun Wang, Zhenyan Guo, Biming Mao, Jianning Liao, Hongchao Guo,* “Lewis-Base-Catalyzed Asymmetric [3+3] Annulation Reaction of Morita–Baylis–Hillman Carbonates: Enantioselective Synthesis of Spirocyclohexenes”, ACS Catal. 2017, 7, 3142–3146. 77. Chang Wang, Hao Jia, Cheng Zhang, Zhenzhen Gao, Leijie Zhou, Chuanhao Yuan, Yumei Xiao, Hongchao Guo,* “Phosphine-Catalyzed Enantioselective [2+4] Cycloaddition to Synthesize Pyrrolidin-2-one Fused Dihydropyrans Using α-Substituted Allenoates as C2 Synthons”, J. Org. Chem. 2017, 82, 633–641. 78. Chunhao Yuan, Leijie Zhou, Miaoren Xia, Zhanhu Sun, Dongqi Wang, Hongchao Guo,* “Phosphine-Catalyzed Enantioselective [4+3] Annulation of Allenoates with C,N-Cyclic Azomethine Imines: Synthesis of Quinazoline-Based Tricyclic Heterocycles”, Org. Lett. 2016, 18, 5644–5647. 79. Honglei Liu, Yang Liu, Chunhao Yuan, Guo-Peng Wang, Shou-Fei Zhu, Yang Wu, Bo Wang, Zhanhu Sun, Yumei Xiao, Qilin Zhou,* Hongchao Guo,*“Enantioselective Synthesis of Spirobarbiturate-Cyclohexenes through Phosphine-Catalyzed Asymmetric [4+2] Annulation of Barbiturate-Derived Alkenes with Allenoates”, Org. Lett. 2016, 18, 1302−1305. 80. Wenjun Yang, Chunhao Yuan, Yang Liu, Biming Mao, Zhanhu Sun, Hongchao Guo,* “[4+3] Cycloaddition of Phthalazinium Dicyanomethanides with Azoalkenes Formed in Situ: Synthesis of Triazepine Derivatives”, J. Org. Chem. 2016, 81, 7597−7603. 81. Yang Wu, Honglei Liu, Lei Zhang, Zhanhu Sun, Yumei Xiao, Jiaxing Huang,* Min Wang,* Hongchao Guo,* “Ag-Catalyzed Diastereoselective [6+3] Cycloaddition of Tropone with Homoserine Lactone-Derived Azomethine Ylides: Synthesis of Tricyclic Spiropiperidines”, RSC Adv. 2016, 6, 73547−73550. 82. Xu Zhang, Chunhao Yuan, Cheng Zhang, Xing Gao, Bo Wang, Zhanhu Sun, Yumei Xiao, Hongchao Guo,* “Thermal [3+2] Cycloaddition of N-Iminoquiazoline Ylides with Allenoates for Synthesis of Tetrahydropyrazoloquinazoline Derivatives”, Tetrahedron 2016, 72, 8274−8281. 83. Yang Wu, Yang Liu, Wenjun Yang, Honglei Liu, Leijie Zhou, Zhanhu Sun, Hongchao Guo,*Chiral Phosphine-Catalyzed Enantioselective [3+2] Annulation of Morita–Baylis–Hillman Carbonates with Cyclic 1-Azadienes: Synthesis of Functionalized Cyclopentenes, Adv. Synth. Catal. 2016, 358, 3517–3521. 84. Yang Liu, Wenjun Yang, Yang Wu, Biming Mao, Xing Gao, Honglei Liu, Zhanhu Sun, Yumei Xiao, Hongchao Guo,* “Asymmetric Construction of Highly Functionalized Spirobarbiturate-Cyclopentenes through Chiral Phosphine-Catalyzed [3+2] Annulation of Morita-Baylis-Hillman Carbonates with Barbiturate-Derived Alkenes”, Adv. Synth. Catal. 2016, 358, 2867−2872. 85. Chunhao Yuan, Leijie Zhou, Zhanhu Sun, Hongchao Guo,* “Phosphine-Catalyzed [3+2] Cycloaddition of Phthalazinium Dicyanomethanides with Allenoates: Highly Efficient Synthesis of 1,2,3,10b-Tetrahydropyrrolo[2,1-a]phthalazine Derivatives”, RSC Adv. 2016, 6, 77931−77936. 86. Zhen Li, Hao Yu, Yang Liu, Leijie Zhou, Zhanhu Sun, Hongchao Guo,* “Phosphane-Catalyzed [3+3] Annulation of C,N-Cyclic Azomethine Imines with Ynones: A Practical Method for Tricyclic Dinitrogen-Fused Heterocycles”, Adv. Synth. Catal. 2016, 358, 1880−1885. 87. Chang Wang, Zhenzhen Gao, Leijie Zhou, Chunhao Yuan, Zhanhu Sun, Yumei Xiao,* Hongchao Guo, “Phosphine-Catalyzed [2+4] Annulation of Allenoates with Thiazolone-Derived Alkenes: Synthesis of Functionalized 6,7-Dihydro-5H-pyrano[2,3-d]thiazoles”, Org. Lett. 2016, 18, 3418−3421. 88. Yumei Xiao, Hongchao Guo,* Ohyun Kwon,* “Nucleophilic Chiral Phosphines: Powerful and Versatile Catalysts for Asymmetric Annulations: Nucleophilic Chiral Phosphines: Powerful and Versatile Catalysts for Asymmetric Annulations”, Aldrichimica Acta 2016, 49, 3−13. 89. Lei Zhang, Honglei Liu, Guanyu Qiao, Zhanfeng Hou, Yang Liu, Yumei Xiao, Hongchao Guo,* “Phosphine-Catalyzed Highly Enantioselective [3+3] Cycloaddition of Morita-Baylis-Hillman Carbonates with C,N-Cyclic Azomethine Imines”, J. Am. Chem. Soc. 2015, 137, 4316–4319. This article was featured in Chinese Journal of Organic Chemistry 2015, 35, 1380–1382. 90. Yang Wu, Guanyu Qiao, Honglei Liu, Lei Zhang, Zhanhu Sun, Yumei Xiao, Hongchao Guo,*“Bronsted Acid-promoted [3+3] Cycloaddition of Azomethine Ylides with Quinone Monoimine: A Practical Method towards Dihydrobenzoxazine Derivatives”, RSC Adv. 2015, 5, 84290−84294. 91. Zhen Li, Hao Yu, Yalin Feng, Zhanfeng Hou, Lei Zhang, Wenjun Yang, Yang Wu, Yumei Xiao, Hongchao Guo,* “Phosphine-Catalyzed [4+3] Cycloaddition Reaction of Aromatic Azomethine Imines with Allenoates”, RSC Adv. 2015, 5, 34481–34485. 92. Zhenzhen Gao, Chang Wang, Chunhao Yuan, Leijie Zhou, Zhanhu Sun, Yumei Xiao,* Hongchao Guo,* “Phosphine-Catalyzed Asymmetric [3+2] Annulation of Chalcones with Allenoates for Enantioselective Synthesis of Functionalized Cyclopentenes”, RSC Adv. 2015, 5, 105359–105362. 93. Chunhao Yuan, Honglei Liu, Zhenzhen Gao, Leijie Zhou, Yalin Feng, Yumei Xiao, Hongchao Guo,* “Cu(I)-Catalyzed Highly Enantioselective [3+3] Cycloaddition between Two Different 1,3-Dipoles, Phthalazinium Dicyanomethanides and Iminoester-Derived Azomethine Ylides”, Org. Lett. 2015, 17, 26−29. 94. Wenjun Yang, Yunpeng Zhang, Shuxian Qiu, Chuanqi Zhao, Lei Zhang, Honglei Liu, Leijie Zhou, Yumei Xiao, Hongchao Guo,* “Phosphine-Catalyzed [4+2] Cycloaddition of Unsaturated Pyrazolones with Allenoates: A Concise Approach toward Spiropyrazolones”, RSC Adv. 2015, 5, 62343−62347. 95. Zhenzhen Gao, Chang Wang, Chunhao Yuan, Leijie Zhou, Yumei Xiao,* Hongchao Guo,* “Phosphine-Catalyzed [4+1] Annulation of 2-Tosylaminochalcones with Allenoates: Synthesis of trans-2,3-Disubstitued Indolines”, Chem. Commun. 2015, 51, 12653−12656. 96. Honglei Liu, Chunhao Yuan, Yang Wu, Yumei Xiao, Hongchao Guo,* “Sc(OTf)3-Catalyzed [3+3] Cycloaddition of Cyclopropane 1,1-Diesters with Phthalazinium Dicyanomethanides”, Org. Lett. 2015, 17, 4220−4223. 97. Honglei Liu, Yang Wu, Yan Zhao, Zhen Li, Lei Zhang, Wenjun Yang, Hui Jiang, Chengfeng Jing, Hao Yu, Bo Wang, Yumei Xiao, Hongchao Guo,* “Metal-Catalyzed [6+3] Cycloaddition of Tropone with Azomethine Ylides: A Practical Access to Piperidine-Fused Bicyclic Heterocycles”, J. Am. Chem. Soc. 2014, 136, 2625–2629. 98. Zhen Li, Hao Yu, Honglei Liu, Lei Zhang, Hui Jiang, Bo Wang, Hongchao Guo,* “Phosphine-Catalyzed [3+2] Cycloaddition Reactions of Azomethine Imines with Electron-Deficient Alkenes: A Facile Access to Dinitrogen-Fused Heterocycles”, Chem. Eur. J. 2014, 20, 1731–1736. 99. Zhilin Yang, Hao Yu, Lei Zhang, Hang Wei, Yumei Xiao, Lanzhen Chen, Hongchao Guo,* “PPh3-Catalyzed Ring-Expansion Reactions of Sulfamate-Derived Cyclic Imines with Acetylenedicarboxylates”, Chem. Asian J. 2014, 9, 313–318. 100. Zhenzhen Gao, Lei Zhang, Zhanhu Sun, Hao Yu, Yumei Xiao,* Hongchao Guo,* “DABCO-catalyzed [3+2] Annulation of Sulfamate-derived Cyclic Imines with Isocyanoacetates: Synthesis of Sulfamate-Fused 2-Imidazoline”, Org. Biomol. Chem. 2014, 12, 5691–5697. 101. Jing Liu, Katlyn K. Meier, Shiliang Tian, Junlong Zhang, Hongchao Guo, Charles E. Schulz, Howard Robinson, Mark J. Nilges, Eckard Münck, Yi Lu,* “Redesigning the Blue Copper Azurin into a Redox-Active Mononuclear Nonheme Iron Protein: Preparation and Study of Fe(II)-M121E Azurin”, J. Am. Chem. Soc. 2014, 136, 12337–12344. 102. Bo Wang, Chunxiao Liu, Hongchao Guo,* “Copper-Catalyzed Enantioselective Propargylic Substitution of Propargylic Acetates with Enamines”, RSC Adv. 2014, 4, 53216–53219. 103. Yumei Xiao, Zhanhu Sun, Hongchao Guo,* Ohyun Kwon,* “Chiral Phosphines in Nucleophilic Organocatalysis”, Beilstein J. Org. Chem. 2014, 10, 2089–2121. 104. Hao Yu, Lei Zhang, Zhen Li, Honglei Liu, Bo Wang, Yumei Xiao, Hongchao Guo,* “Phosphine-Catalyzed [4+2] Cycloaddition of Sulfamate-Derived Cyclic Imines with Allenoates: Synthesis of Sulfamate-Fused Tetrahydropyridines”, Tetrahedron 2014, 70, 340–348. 105. Zhen Li, Hao Yu, Lei Zhang, Honglei Liu, Risong Na, Qinghua Bian,* Min Wang,* Hongchao Guo,* “Thermal [3+2] Cycloaddition Reaction of N-Acyliminophenanthridinium Betaine with Allenoates: Facile Access to Phenanthridine-Fused Tetracyclic Heterocycles”, Lett. Org. Chem. 2014, 11, 220–224. 106. Lei Zhang, Hao Yu, Zhilin Yang, Honglei Liu, Zhen Li, Junhong Guo, Yumei Xiao, Hongchao Guo,* “Phosphine-Catalyzed [3+2] Cycloaddition of Morita-Baylis-Hillman Carbonates with Sulfamate-Derived Cyclic Imines”, Org. Biomol. Chem. 2013, 11, 8235–8240. 107. Hao Yu, Lei Zhang, Zhilin Yang, Zhen Li, Yan Zhao, Yumei Xiao, Hongchao Guo,* “Phosphine-Catalyzed [3+2] Cycloaddition of Sulfamate-Derived Cyclic Imines with Allenoate: Synthesis of Sulfamate-Fused Dihydropyrroles”, J. Org. Chem. 2013, 78, 8427–8436. 108. Hongchao Guo,* Honglei Liu, Fu-Lin Zhu, Risong Na, Hui Jiang, Yang Wu, Lei Zhang, Zhen Li, Hao Yu, Bo Wang, Yumei Xiao, Xiang-Ping Hu,* Min Wang, “Enantioselective Copper-Catalyzed [3+3] Cycloaddition of Azomethine Ylides with Azomethine Imines”, Angew. Chem. Int. Ed. 2013, 52, 12641–12645. 109. Lei Zhang, Chengfeng Jing, Honglei Liu, Bo Wang, Zhen Li, Hui Jiang, Hao Yu, Hongchao Guo,* “Thermal [3+2] Cycloaddition of Aromatic Azomethine Imines with Allenoates”, Synthesis 2013, 45, 53–64. 110. Changkui Fu, Chongyu Zhu, Shiqi Wang, Honglei Liu, Yun Zhang, Hongchao Guo, Lei Tao,* Yen Wei,* “One-pot Synthesis of Optically Active Polymer via Concurrent Cooperation of Enzymatic Resolution and Living Radical Polymerization”, Polym. Chem. 2013, 4, 264–267. 111. Yang Wu, Hongchao Guo,* “Synthesis of Allenoates”, Chemical Reagents 2013, 35, 1085–1088. 112. Risong Na, Bo Wang, Honglei Liu, Qinghua Bian, Jiangchun Zhong, Min Wang,* Hongchao Guo,* “Synthesis and Application of Novel Dithiane Alcohol Ligand Based on Chiral Cyclopropane-backbone for Asymmetric Ethylation of Aromatic Aldehydes”, Lett. Org. Chem. 2012, 9, 622–627. 113. Hui Jiang, Risong Na, Lei Zhang, Honglei Liu, Zhen Li, Bo Wang, Hongchao Guo,* “Samarium Diiodide Mediated Highly Diastereoselective Conjugate Reduction of the alpha,beta-Unsaturated Ester Moiety in Heterocyclic Compounds”, Synthesis 2012, 44, 3633–3638. 114. Chengfeng Jing, Risong Na, Honglei Liu, Lei Zhang, Jun Liu, Min Wang, Jiangchun Zhong,* Ohyun Kwon, Hongchao Guo,* “Phosphine-Catalyzed [3+2] and [4+3] Annulation Reactions of C,N-Cyclic Azomethine Imines with Allenoates”, Adv. Synth. Catal. 2012, 354, 1023–1034. 115. Risong Na, Zhen Li, Honglei Liu, Jun Liu, Ming-An Wang, Min Wang, Jiangchun Zhong, Hongchao Guo,* “Thermal [3+2] Cycloaddition Reaction of Azomethine Imines with Allenoates for Dinitrogen-fused Heterocycles”, Tetrahedron 2012, 68, 2349–2356. 116. Jun Liu, Honglei Liu, Risong Na, Guiyong Wang, Min Wang, Jiangchun Zhong,* Hongchao Guo,* “Phosphine-Catalyzed [3+2] and [3+3] Annulations of Azomethine Imines with Ethyl 2-Butynoate”, Chem. Lett. 2012, 41, 218–230. 117. Bing Zheng, Shuoning Li, Jianyou Mao, Bo Wang, Qinghua Bian, Shangzhong Liu, Jiangchun Zhong,* Hongchao Guo, Min Wang,* “Highly Enantioselective Addition of 1,3-Diynes to Aldehydes Catalyzed by a Zinc-Amino Alcohol Complex”, Chem. Eur. J. 2012, 18, 9208–9211. 118. Xi Wu, Risong Na, Honglei Liu, Jun Liu, Min Wang, Jiangchun Zhong,* Hongchao Guo,* “Sequential [3+2] Cycloaddition/Rearrangement Reaction of Imidazolone Nitrones and Allenoates for the Efficient Synthesis of Functionalized Imidazolidinone”, Tetrahedron Lett. 2012, 53, 342–344. 119. Hongchao Guo, Kuiling Ding,* “Self-Supported Chiral Catalysts for Heterogeneous Asymmetric Catalysis”, Chimia 2011, 65, 932–938. 120. Risong Na, Chengfeng Jing, Qihai Xu, Hui Jiang, Xi Wu, Jiayan Shi, Jiangchun Zhong, Min Wang, Diego Benitez, Ekaterina Tkatchouk, William A. Goddard, III, Hongchao Guo,* Ohyun Kwon,* “Phosphine-Catalyzed Annulations of Azomethine Imines: Allene-Dependent [3+2], [3+3], [4+3], and [3+2+3] Pathways”, J. Am. Chem. Soc. 2011, 133, 13337–13348. 121. Bing Zheng, Min Wang, Zhiyuan Li, Qinghua Bian, Jianyou Mao, Shuoning Li, Shangzhong Liu, Mingan Wang, Jiangchun Zhong,* Hongchao Guo,* “Asymmetric Henry reaction catalyzed by a Zn–amino alcohol system”, Tetrahedron: Asymmetry 2011, 22, 1156–1160. 122. Jing Nie, Hongchao Guo, Dominique Cahard, Jun-An Ma,* “Asymmetric Construction of Stereogenic Carbon Centers Featuring a Trifluoromethyl Group from Prochiral Trifluoromethylated Substrates”, Chem. Rev. 2011, 111, 455–529. 123. Zhiyuan Li, Min Wang, Qinghua Bian, Bing Zheng, Jianyou Mao, Shuoning Li, Shangzhong Liu, Ming-an Wang, Jiangchun Zhong,* Hongchao Guo,* “Highly Enantioselective Addition of Trimethylsilylacetylene to Aldehydes Catalyzed by a Zinc-Amino-Alcohol Complex”, Chem. Eur. J. 2011, 17, 5782–5786. 124. Hongchao Guo, Kuiling Ding, “Indium Tribromide”, Encyclopedia of Reagents for Organic Synthesis, 2011. 125. Book Chapter: Hongchao Guo, Kuiling Ding, “Self-Supported Chiral Catalysts”, In Catalytic Methods in Asymmetric Synthesis: Advanced Materials, Techniques, and Applications, First Edition. Michelangelo Gruttadauria, Franceso Giacalone, Eds., John Wiley & Sons, Inc. 2011, Chapter 5, p.257–290. 126. Hongchao Guo, Qihai Xu, Ohyun Kwon,* “Phosphine-Promoted [3+3] Annulation of Aziridines with Allenoates: A Facile Entry into Highly Functionalized Tetrahydropyridines”, J. Am. Chem. Soc. 2009, 131, 6318–6319. This article was selected by the Editorial Board of Synfacts for its important insights, Synfacts 2009, 748, was also highlighted by Chemtracts, Chemtracts-Organic Chemistry 2010, 23, 111–114. 127. Manfred T. Reetz,* Hongchao Guo, Jun-An Ma, Richard Goddard, Richard J. Mynott, “Helical Triskelion Monophosphites as Ligands in Asymmetric Catalysis”,J. Am. Chem. Soc.2009, 131, 4136–4142. 128. Bing Zheng, Shicong Hou, Zhiyuan Li, Hongchao Guo, Jiangchun Zhong,* Min Wang,* “Enantioselective Synthesis of Quaternary Stereogenic Centers through Catalytic Asymmetric Addition of Dimethylzinc to alpha-Ketoesters with Chiral cis-Cyclopropane-Based Amide Alcohol as Ligand”, Tetrahedron: Asymmetry 2009, 20, 2125–2129. 129. Book Chapter: Hongchao Guo, Kuiling Ding,* “New Advance in Combinatorial Asymmetric Catalysis”, In Asymmetric Catalysis: New Concepts and Methods”, K. L. Ding, Q. H. Fan, Eds., Chemical Industry Press, Beijing, 2009, Chapter 14, p.431–463. 130. Jinshan Gao, Hongchao Guo,* Shangzhong Liu, Min Wang,* “Efficient Soluble Polymer-supported Tartrate/Ti Catalyst for Asymmetric Oxidation of Prochiral Sulfides”, Tetrahedron Lett. 2007, 48, 8453–8455. 131. Jiangchun Zhong, Hongchao Guo, Ming-An Wang, Mingming Yin, Min Wang,* “Asymmetric Diethylzinc Addition and Phenyl Transfer to Aldehydes Using Chiral cis-Cyclopropane-based Amino Alcohols”, Tetrahedron: Asymmetry 2007, 18, 734–741. 132. Manfred T. Reetz,* Hongchao Guo, “Transposition of Allylic Alcohols into Carbonyl Compounds Catalyzed by Rhodium/Phosphinine-complexes”, Synlett 2006, 2127–2129. 133. Jiangchun Zhong, Ming-An Wang, Hongchao Guo, Mingming Yin, Qinghua Bian, Min Wang,* “Design and Synthesis of 1,4-Amino Alcohol Ligands with a Chiral Cyclopropane Backbone for Asymmetric Diethylzinc Addition to Aromatic Aldehydes”, Synlett 2006, 1667–1670. 134. Jun Liu, Qinghua Bian, Ming-An Wang, Hongchao Guo,* Min Wang,* “Synthesis and Unexpected Ring-Opening Reaction of a New TADDOL Analogue with Chiral Cyclopropane Ring as Backbone”, Chin. Chem. Lett. 2006, 17, 606–608. 135. Hongchao Guo, Jun-An Ma,* “Catalytic Asymmetric Tandem Transformations Triggered by Conjugate Additions”, Angew. Chem. Int. Ed. 2006, 45, 354–366. 136. Manfred T. Reetz,* Hongchao Guo, “Mixtures of Monodentate P-Ligands as a Means to Control the Diastereoselectivity in Rh-Catalyzed Hydrogenation of Chiral Alkenes”, Beilstein J. Org. Chem. 2005, 1:3. 137. Hongchao Guo, Zheng Wang, Kuiling Ding,* “PEG-polymer-Supported Liquid-phase Combinatorial Synthesis of Structurally Diverse 2,3-Dihydro-4-pyridones”, Synthesis 2005, 1061–1068. 138. Xisheng Wang, Xingwang Wang, Hongchao Guo, Zheng Wang, Kuiling Ding,* “Self-Supported Heterogeneous Titanium Catalysts for Enantioselective Carbonyl-ene and Sulfoxidation Reactions”, Chem. Eur. J. 2005, 11, 4078–4088. 139. Xueyan Shi, Hongchao Guo, Min Wang,* “Enantioseparation of Chiral Epoxides Using Four New Cyclodextrin Derivatives as Chiral Stationary Phases of Capillary Gas Chromatography ”, Anal. Chim. Acta 2005, 553, 43–49. 140. Kuiling Ding,* Hongchao Guo, Xin Li, Yu Yuan, Yi Wang, “Synthesis of NOBIN Derivatives for Asymmetric Catalysis”, Topics in Catalysis 2005, 35, 105–116. 141. Kuiling Ding,* Xin Li, Baoming Ji, Hongchao Guo, Masato Kitamura, “Ten Years of Research on NOBIN Chemistry”, Curr. Org. Synth. 2005, 2, 499–545. 142. Book Chapter: Hongchao Guo, Kuiling Ding,* “Asymmetric Catalysis”, In Advance in Modern Organic Synthetic Chemistry, Y. L. Wu, S. M. Ma, L. X. Dai, Eds., Chemical Industry Press, Beijing, 2005, Chapter 7, p.174–216. 143. Book Chapter: Hongchao Guo, Kuiling Ding,* “Combinatorial Asymmetric Catalysis”, In Asymmetric Organic Reactions, Y. M. Li, Q. H. Fan, A. S. C. Chan, Eds., Chemical Industry Press, Beijing, 2005, Chapter 4, p.39–91. 144. Hongchao Guo, Xingwang Wang, Kuiling Ding,* “Assembled Enantioselective Catalysts for Carbonyl-ene Reactions”, Tetrahedron Lett. 2004, 45, 2009–2012. Highlighted by Angew. Chem. Int. Ed. 2004, 43, 5726–5729. 145. Hongchao Guo, Kuiling Ding,* Lixin Dai, “Recent Advances in Catalytic Asymmetric Hydrogenation: Renaissance of the Monodentate Phosphorus Ligands ”, Chin. Sci. Bull. 2004, 49, 2003–2016. 146. Hongchao Guo, Kuiling Ding, Lixin Dai,* “A New Principle in Combinatorial Asymmetric Transition-Metal Catalysis: Mixtures of Chiral Monodentate P Ligands”, a comment paper for Prof. M. T. Reetz’s research published in Angew. Chem. Int. Ed. 2003, 42, 790–793, Chemtracts 2004, 17, 57–66. 147. Hongchao Guo,* Xueyan Shi, Xian Wang, Shangzhong Liu, Min Wang,* “Liquid-phase Synthesis of Chiral Tartrate Ligand Library for Enantioselective Sharpless Epoxidation of Allylic Alcohols”, J. Org. Chem. 2004, 69, 2042–2047. 148. Shicong Hou, Zhiqiang Zhou, Zhen Qiao, Hongchao Guo, Xueyan Shi, Min Wang,* “Enantioseparation of Acaricide Hexythiazox by High Performance Liquid Chromatography”, Chin. J. Anal. Chem. 2004, 32, 126–126. 149. Hongchao Guo, Kuiling Ding,* “Liquid-phase Synthesis of 2,3-Dihydro-4-Pyridones: One-Pot Three-component Aza Diels-Alder Reaction of Danishefsky’s Diene with Aldehydes and PEG-supported Amine”, Tetrahedron Lett. 2003, 44, 7103–7106. 150. Xueyan Shi, Zhen Qiao, Hongchao Guo, Min Wang,* “Capillary Gas Chromatographic Separation of Enantiomers of 2-Phenyl-1-Cyclopropanecarboxylate”, Chin. J. Chromatography 2003, 21, 281–284. 151. Shicong Hou, Zhiqiang Zhou, Zhen Qiao, Hongchao Guo, Xueyan Shi, Min Wang,* “Separation of the Enantiomers of Tebuconazole and Its Potential Impurities by High-Performance Liquid Chromatography with a Cellulose Derivative-Based Chiral Stationary Phase”, Chromatographia 2003, 57, 177–180. 152. Shicong Hou, Min Wang, Zhen Qiao, Hongchao Guo, Xueyan Shi, Zhiqiang Zhou,* “Direct Resolution of Flamprop-methyl Enantiomers by HPLC”, Chin. J. Appl. Chem. 2003, 20, 505–507. 153. Hongchao Guo, Xueyan Shi, Zhen Qiao, Shicong Hou, Min Wang,* “Efficient Soluble Polymer-Supported Sharpless Alkene Epoxidation Catalyst”, Chem. Commun.2002, 118–119. 154. Hongchao Guo, Xueyan Shi, Min Wang,* “Soluble Polymer-Supported Reagents and Catalysts”, Progress In Chemistry 2002, 14, 391–397. 155. Hongchao Guo, Xueyan Shi, Zhen Qiao, Shicong Hou, Min Wang,* “The Synthesis and Application of A New Poly(ethylene glycol) as CGC Stationary Phase”, J. Instrumental Anal. 2002, 21, 88–90. 156. Xueyan Shi, Hongchao Guo, Min Wang,* Shuren Jiang, “Synthesis of 3 New Cyclodextrin Derivatives and Their Application as Chiral Stationary Phases in the Determination of Optical Purity by Capillary Gas-Chromatography”, Chromatographia 2002, 56, 755–759. 157. Xueyan Shi, Hongchao Guo, Min Wang,* Shuren Jiang, “Capillary Gas-Chromatography Separation of Pyrethroic Acid Methyl-Esters Using 4 Acylated Cyclodextrin Derivatives as Chiral Stationary Phases”, Chromatographia 2002, 56, 207–211. 158. Xueyan Shi, Hongchao Guo, Zhen Qiao, Shicong Hou, Min Wang,* “The Enantiomer Separation of Allethrone and Propargyllone Using 2 Long-Chain Acylated beta-Cyclodextrin Derivatives as CGC Capillary Stationary Phases”, Chin. Chem. Lett. 2002, 13, 973–976. 159. Xueyan Shi, Min Wang,* Hongchao Guo, Zhen Qiao, Yun Ling, Nan Li, Wenge Jin, Jingmei Zhou, “Enantioseparation of Several Pyrethroic Acid Methyl Esters on Capillary Gas Chromatography”, Chin. J. Anal. Chem. 2002, 30, 1293–1297. 160. Shicong Hou, Min Wang,* Zhiqiang Zhou, Zhen Qiao, Hongchao Guo, Xueyan Shi, “Separation of Enantiomers of a Benzimidazole Derivative by High Performance Liquid Chromatography”, Chin. J. Pesti. Sci. 2002, 4, 71–74. 161. Shicong Hou, Min Wang,* Zhiqiang Zhou, Zhen Qiao, Hongchao Guo, Xueyan Shi, “Preparation of Cellulose-Based Chiral Stationary Phase and Enantioseparation of Ethoxyfen-Ethyl by High Performance Liquid Chromatography”, Chin. J. Chromatography 2002, 20, 537–539. 162. Maojiang Wu, Hongchao Guo, Min Wang,* “Liquid-phase Synthesis Methods in Organic Chemistry”, Chemistry Online (Huaxue Tongbao) 2002, 65, w017. 163. Xueyan Shi, Hongchao Guo, Min Wang,* Wenge Jin, Jingmei Zhou, “The Synthesis of A New Cyclodextrin Derivative and Its Application in Determination of Optical Purity as CGC Chiral Stationary Phases”, Chin. J. Chromatography 2002, 20, 34–36. 164. Hongchao Guo, Shangzhong Liu, Xuetai Hou, Min Wang,* “Isomerization of 4-Amino-6- tert-butyl-3-methylthio-1,2,4-triazin-5(4H)-one with Base”, Chin. Chem. Lett. 2001, 12, 753–756. 165. Xueyan Shi, Hongchao Guo, Zhen Qiao, Shicong Hou, Min Wang,* “The Study on the Determination of the Optical Purity of Permethrinic Acid by Capillary Gas Phase Chromatography”, Chin. J. Pesti. Sci. 2001, 3(4), 93–96. 166. Xian Wang, Hongchao Guo, Xuetai Hou, Min Wang,* “The Synthesis of Impurities in Full-analysis of Ethoprophos”, Pesticide 2001, 40(12), 21–22. 167. Hongchao Guo, Min Wang,* “The Application of Binaphthyl Derivatives as Chiral Ligand in Asymmetric Hydrogenation”, Chin. J. Org. Chem. 2000, 20, 486–498.
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